Comparative study of the structural and magnetic properties of Mn1/3NbS2 and Cr1/3NbS2

被引:17
|
作者
Hall, A. E. [1 ]
Loudon, J. C. [2 ]
Midgley, P. A. [2 ]
Twitchett-Harrison, A. C. [2 ]
Holt, S. J. R. [1 ]
Mayoh, D. A. [1 ]
Tidey, J. P. [3 ]
Han, Y. [1 ]
Lees, M. R. [1 ]
Balakrishnan, G. [1 ]
机构
[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[2] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England
[3] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
来源
PHYSICAL REVIEW MATERIALS | 2022年 / 6卷 / 02期
基金
英国工程与自然科学研究理事会;
关键词
TRANSITIONS;
D O I
10.1103/PhysRevMaterials.6.024407
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We compare the magnetism of single crystals of the intercalated transition metal dichalcogenides Cr1/3NbS2 and Mn1/3NbS2 using techniques such as dc and ac susceptibility and Lorentz transmission electron microscopy (LTEM). We present a detailed structural investigation of these materials using electron and single-crystal x-ray diffraction measurements to show how substitutional disorder and stacking faults can manifest in Cr1/3NbS2 and Mn1/3NbS2, and give rise to additional superlattice reflections in diffraction patterns acquired from Mn1/3NbS2. Magnetic susceptibility and LTEM measurements show Cr1/3NbS2 displays chiral helimagnetism below its magnetic ordering temperature (T-C) of 111 K, while there is no evidence that Mn1/3NbS2 exhibits helimagnetic ordering below its transition temperature T-C = 45 K.
引用
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页数:11
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