CeO2 quantum dots modified electrode for detecting hydrogen peroxide

被引:8
|
作者
Wang, Yaping [1 ]
Qian, Junchao [2 ]
Chen, Zhigang [2 ]
Wang, Chencheng [1 ]
Liu, Chengbao [2 ]
Yang, Yue [3 ]
Wu, Zhiyi [4 ]
Song, Yenan [5 ]
机构
[1] Jiangsu Univ, Dept Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Suzhou Univ Sci & Technol, Jiangsu Key Lab Environm Funct Mat, Suzhou 215009, Peoples R China
[3] East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
[4] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China
[5] East China Normal Univ, Engn Res Ctr Nanophoton & Adv Instrument, Sch Phys & Mat Sci, Minist Educ, Shanghai 200062, Peoples R China
基金
中国国家自然科学基金;
关键词
Cerium oxides; Hydrogen peroxide; Modified electrode; Quantum dots; Electrochemical methods; ELECTROCHEMICAL SENSOR; CARBON NANOTUBES; IMMUNOSENSOR; NANOCOMPOSITES; ACETAMINOPHEN; STRATEGY;
D O I
10.1016/j.inoche.2019.01.015
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This study describes the fabrication of a sensitive modified electrode for detecting hydrogen peroxide. The glassy carbon surface was modified with a composite containing CeO2 quantum dots and carbon sheets. The ultra-small grain size of nanoparticle endows the electrode with excellent electrocatalytic activity. As a result, the electrode shows electrocatalytic reduction activity toward H2O2 at a potential of -0.5 V. The CeO2 quantum dots sensor shows a satisfactory performance for detecting hydrogen peroxide with a linear range of 2 ppm-1000 ppm, and a limit of detection (LOD) of 900 ppb. These findings show that CeO2 quantum dots have a great potential for applications in electrochemical sensing.
引用
收藏
页码:62 / 68
页数:7
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