Homogeneous biocatalysis in both fluorous biphasic and supercritical carbon dioxide systems

被引：15
|
作者：
Hobbs, Helen R. [1 ]
Kirke, Helen M. [1 ]
Poliakoff, Martyn [1 ]
Thomas, Neil R. [1 ]
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期
关键词：
biocatalysis; biphasic catalysis; enzymes; ion pairs; supercritical fluids;
D O I：
10.1002/anie.200701488
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) HIP to be green: Cytochrome c and α-chymotrypsin (CMT) can be solubilized in either fluorous solvents or supercritical CO 2 by hydrophobic ion pairing (HIP) with perfluorinated anionic surfactants (Krytox 157 FSL, KDP 4606). A model system for homogeneous fluorous biphasic biocatalysis involving the CMT-KDP complex in hexane/ perfluoromethylcyclohexane is reported that simplifies both product separation and recycling of the biocatalyst. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7860 / 7863
页数：4
相关论文
共 50 条
  • [1] Toward Green Processes for Fine Chemicals Synthesis: Biocatalysis in Ionic Liquid-Supercritical Carbon Dioxide Biphasic Systems
    Lozano, Pedro
    De Diego, Teresa
    Gmoeuh, Said
    Vaultier, Michel
    Iborra, Jose L.
    IONIC LIQUIDS IN ORGANIC SYNTHESIS, 2007, 950 : 209 - 223
  • [2] Towards green processes for fine chemicals synthesis: Biocatalysis in ionic liquid/supercritical carbon dioxide biphasic systems.
    Lozano, P
    De Diego, T
    Gmouh, S
    Vaultier, M
    Iborra, JL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U65 - U66
  • [3] A continuous process concept for homogeneous catalysis in fluorous biphasic systems
    Perperi, E
    Huang, YL
    Angeli, P
    Manos, G
    Mathison, CR
    Cole-Hamilton, DJ
    Adams, DA
    Hope, EG
    CHEMICAL ENGINEERING SCIENCE, 2004, 59 (22-23) : 4983 - 4989
  • [4] Enzymatic catalysis in ionic liquids and supercritical carbon dioxide biphasic systems
    Lozano, Pedro
    De Diego, Teresa
    Iborra, Jose L.
    CHIMICA OGGI-CHEMISTRY TODAY, 2007, 25 (06) : 76 - 79
  • [5] Recent progress in biocatalysis using supercritical carbon dioxide
    Matsuda, Tomoko
    JOURNAL OF BIOSCIENCE AND BIOENGINEERING, 2013, 115 (03) : 233 - 241
  • [6] Characterisation of a novel support for biocatalysis in supercritical carbon dioxide
    Al-Duri, B
    Goddard, R
    Bosley, J
    JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2001, 11 (4-6) : 825 - 834
  • [7] Progress in the study of biphasic systems prompted by supercritical carbon dioxide and their applications to organic syntheses
    Yue, Xiao-Dong
    He, Liang-Nian
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2006, 26 (05) : 610 - 617
  • [8] Highly Fluorous Complexes of Ruthenium and Osmium and Their Solubility in Supercritical Carbon Dioxide
    Berven, Bradley M.
    Koutsantonis, George A.
    Skelton, Brian W.
    Trengove, Robert D.
    White, Allan H.
    INORGANIC CHEMISTRY, 2009, 48 (24) : 11832 - 11842
  • [9] New advances in applications of ionic liquid/supercritical carbon dioxide biphasic systems to organic synthesis
    Fan, Hui-Hua
    Wang, A-Zhong
    Yang, Shao-Rong
    Jiang, Huan-Feng
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2008, 28 (05) : 768 - 774
  • [10] Homogeneous catalysis in supercritical carbon dioxide and fluoroform.
    Jessop, PG
    Brown, R
    Wynne, D
    Ikariya, T
    Noyori, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U98 - U98
12345