Spectroscopic study of DHDA complex formation of d- and f-electron metal ions in methanol solution

被引:2
|
作者
Staninski, K
Lis, S
Pietraszkiewicz, M
机构
[1] Adam Mickiewicz Univ Poznan, Fac Chem, Dept Rare Earths, PL-60780 Poznan, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
lanthanide complexes; spectrophotometric study; stability constants; fluorescence spectra;
D O I
10.1007/s10895-005-2822-x
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Synthesis and spectral characterization of N,N'-Bis(2,4-dihydroxobenzylidene)1,2-diaminobenzene (DHDA) complexes with chosen f- and d-metal ions are described. Physico-chemical properties of a series of complexes: DHDA-La(NO3)(3), DHDA-Eu(NO3)(3). DHDA-Yb(NO3)(3), DHDA-Cu(NO3)(2), DHDA-Zn(NO3)(2), DHDA-Co(NO3)(2), were studied in methanol solution using UV-VIS, IR and fluorescence spectroscopy. Based on the absorption spectra the conditional stability constants of the metal complexes were determined.
引用
收藏
页码:493 / 497
页数:5
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