Development of the "PERFECT" direct fluorination method and its industrial applications

被引：18

作者：

Okazoe, Takashi ^{[1
]}

机构：

[1] Asahi Glass Co Ltd, Technol Planning Off, Chiyoda Ku, Tokyo 1008405, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2015年 / 174卷

关键词：

The PERFECT' method; Acyl fluoride; Direct fluorination; Perfluorination; Fluorine; PHASE DIRECT FLUORINATION; PERFLUORINATED COMPOUNDS; ELEMENTAL FLUORINE; MONOMER; CHEMISTRY; MEMBRANE; ROUTE;

D O I：

10.1016/j.jfluchem.2014.09.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The "PERFECT" direct fluorination method for the preparation of perfluorinated compounds, which has been developed and is beeing used for manufacturing in Asahi Glass Co., Ltd., and the comparison with other liquid-phase direct fluorination methods are reviewed. A key step in the synthetic route is a liquid-phase direct fluorination reaction with elemental fluorine. Direct fluorination of a partially-fluorinated ester, which was prepared from a hydrocarbon alcohol and a perfluoroacyl fluoride, followed by thermolysis, gave a corresponding perfluorinated product and the starting perfluoroacyl fluoride recovered. The perfluorinated product is a precursor of various perfluorinated building blocks. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：120 / 131

页数：12

共 50 条

[1] Direct fluorination of polymers - From fundamental research to industrial applications
Kharitonov, A. P.
PROGRESS IN ORGANIC COATINGS, 2008, 61 (2-4) : 192 - 204
[2] Direct fluorination of polymers: Fundamental features and possible industrial applications.
Kharitonov, AP
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U73 - U73
[3] A synthetic method for the production of perfluorinated building blocks The "perfect" direct fluorination technique
Okazoe, Takashi
CHIMICA OGGI-CHEMISTRY TODAY, 2010, 28 (02) : 29 - 32
[4] METHOD HARNESSES DIRECT FLUORINATION
不详
CHEMICAL & ENGINEERING NEWS, 1970, 48 (02) : 40 - &
[5] Practical applications of the direct fluorination of polymers
Kharitonov, AP
JOURNAL OF FLUORINE CHEMISTRY, 2000, 103 (02) : 123 - 127
[6] DIRECT FLUORINATION AS A USEFUL SYNTHETIC METHOD
LAGOW, RJ
LIU, EKS
ADCOCK, JL
MARASCHIN, NJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, : 32 - 32
[7] A knowledge discovery method and its industrial applications
Hao, W
PROCEEDINGS OF THE 3RD WORLD CONGRESS ON INTELLIGENT CONTROL AND AUTOMATION, VOLS 1-5, 2000, : 369 - 372
[8] Development and applications of new fluorination methods
Sanford, Melanie
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[9] Development of the theory of countercurrent extraction and its industrial applications
Yan Chun-Hua
Wu Sheng
Liao Chun-Sheng
Jia Jiang-Tao
Cheng Fu-Xiang
Wang Song-Ling
Zhang Bo
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (08) : 1200 - 1205
[10] ZigBee good, but not perfect fit for industrial applications
不详
CONTROL ENGINEERING, 2005, 52 (10) : 30 - 30

← 1 2 3 4 5 →