Transformation of 1-D chiral-chained titanium phosphate to 2-D layer structure through a 1-D zigzag chain

被引：0

作者：

Chen, C ^{[1
]}

Yang, YL ^{[1
]}

Li, WS ^{[1
]}

Liu, YL ^{[1
]}

Yi, Z ^{[1
]}

Guo, YH ^{[1
]}

Pang, WQ ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synthesis & Preparat Chem, Changchun 130012, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2005年 / 21卷 / 04期

关键词：

transformation; titanium phosphate; mechanism; rational design;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transformation of titanium phosphate from 1-D chiral- chain (JTP-A) to 2-D layer (TP-J1) has been carefully investigated. Through a hydrolysis-condensation self-assembly pathway, the crystals of TP-J1 can be obtained from the JTP-A phase under hydrothermal conditions. An intermediate material with zigzag chain during the transformation was observed by XRD characterization. A hypothesis of the transformation mechanism is also described in this article. It is noteworthy that ethylenediamine plays an important role in the transformation.

引用

页码：411 / 414

页数：4

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