3D Chiral Microporous (10,3)-a Topology Metal-Organic Framework Containing Large Helical Channels

被引：19
|
作者：
Li, Mei-Na [1 ]
Du, Dong-Ying [1 ]
Yang, Guang-Sheng [1 ]
Li, Shun-Li [1 ]
Lan, Ya-Qian [1 ]
Shao, Kui-Zhan [1 ]
Qin, Jun-Sheng [1 ]
Su, Zhong-Min [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci,Inst Funct Mat Chem, Changchun 130024, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 06期
基金：
中国国家自然科学基金;
关键词：
COORDINATION POLYMERS; 3-DIMENSIONAL NETWORK; CRYSTAL-STRUCTURES; HYDROGEN STORAGE; BUILDING-BLOCK; DESIGN; COMPLEXES; NETS; CONSTRUCTION; CADMIUM(II);
D O I：
10.1021/cg2002223
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new 3D chiral metal organic framework [Co-2(BTT)(OH)(H2O)(5)] center dot 5CH(3)OH center dot 6DMA (1) has been synthesized using an achiral tritopic bridging ligand, 1,3,5-tris(2H-tetrazol-5-yl)benzene (H3BTT). 1 possesses a (10,3)-a net containing large helical channels of 17.43 angstrom and exhibits a high solvent-accessible volume (calculated 79%). The N-2 adsorption and magnetic properties for 1 have been examined.
引用
收藏
页码：2510 / 2514
页数：5
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