Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)

被引：0
|
作者：
Oreshkina, A. V. [1 ]
Kaziev, G. Z. [1 ]
Steblevskii, A. V. [2 ]
机构：
[1] Moscow State Pedag Univ, Moscow 119991, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 56卷 / 04期
关键词：
Cobalt Nitrate; Cadmium Acetate; Heteropoly Compound; Chromium Nitrate; Ammonium Paramo Lybdate;
D O I：
10.1134/S0036023611040231
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hydrogen hexamolybdochromate(III) of compositions [Cd(NH3)(6)] center dot H[CoMo6O18(OH)(6)] center dot 6H(2)O (I) and [Cd(NH3)(6)] center dot H[CrMo6O18(OH)(6)] center dot 6H(2)O (II), respectively, were synthesized and studied by mass spectroscopy, thermo-gravimetry, X-ray powder diffraction, and IR spectroscopy. Crystals of I and II are monoclinic. For I: a = 10.79 , b = 3.70 , c = 11.95 , beta = 91.05A degrees, V = 470.12 (3), rho(calc) = 2.37 g/cm(3), Z = 2; and for II: a = 10.80 , b = 3.68 , c = 11.97 , beta = 91.07A degrees, V = 468.98 (3), rho(calc) = 2.36 g/cm(3), Z = 2.
引用
收藏
页码：612 / 615
页数：4
相关论文
共 50 条
  • [1] Synthesis and study of hexaamminecadmium hydrogen hexamolybdocobaltate(III) and hexamolybdochromate(III)
    A. V. Oreshkina
    G. Z. Kaziev
    A. V. Steblevskii
    Russian Journal of Inorganic Chemistry, 2011, 56 : 612 - 615
  • [2] Synthesis and study of gallium hexamolybdocobaltate(III)
    Kaziev, GZ
    Dutov, AA
    Quinones, SH
    Bel'skii, VK
    Zavodnik, VE
    De Ita, A
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (07) : 972 - 976
  • [3] Synthesis and study of gallium hexamolybdochromate(III)
    Kaziev, G.Z.
    Qignones, S.O.
    Bel'skij, V.K.
    Zavodnik, V.E.
    Osminkina, I.V.
    De, Ita, A.
    Zhurnal Neorganicheskoj Khimii, 2002, 47 (03): : 389 - 396
  • [4] Synthesis and study of gallium hexamolybdochromate(III)
    Kaziev, GZ
    Qignones, SO
    Bel'skii, VK
    Zavodnik, VE
    Osminkina, IV
    de Ita, A
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (03) : 335 - 340
  • [5] Synthesis and physicochemical study of hexamminechromium(III) hexamolybdocobaltate
    Oreshkina, A. V.
    Kaziev, G. Z.
    Holguin Quinones, S.
    Milyutina, A. D.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (07) : 763 - 765
  • [6] Synthesis and physicochemical study of hexamminechromium(III) hexamolybdocobaltate
    A. V. Oreshkina
    G. Z. Kaziev
    S. Holguin Quinones
    A. D. Milyutina
    Russian Journal of Inorganic Chemistry, 2013, 58 : 763 - 765
  • [7] Synthesis and study of tetraamminecobalt hydrogen hexamolybdochromate
    A. V. Oreshkina
    G. Z. Kaziev
    A. V. Steblevskii
    E. I. Myasnikova
    Russian Journal of Inorganic Chemistry, 2010, 55 : 368 - 369
  • [8] Synthesis and study of tetraamminecobalt hydrogen hexamolybdochromate
    Oreshkina, A. V.
    Kaziev, G. Z.
    Steblevskii, A. V.
    Myasnikova, E. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (03) : 368 - 369
  • [9] Selective Oxidation of Alcohols to Aldehydes by Hydrogen Peroxide Using Hexamolybdochromate(III) as Catalyst
    Mardur, S. P.
    Gokavi, G. S.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2010, 7 (02) : 441 - 446
  • [10] Selective oxidation of alcohols to aldehydes by hydrogen peroxide using hexamolybdochromate(III) as catalyst
    S. P. Mardur
    G. S. Gokavi
    Journal of the Iranian Chemical Society, 2010, 7 : 441 - 446
12345