New chiral ligands from isosorbide: application in asymmetric transfer hydrogenation

被引：25

作者：

Guillarme, Stephane ^{[1
]}

Nguyen, Thi Xuan Mai ^{[1
]}

Saluzzo, Christine ^{[1
]}

机构：

[1] Univ Maine, UCO2M UMR CNRS 6011, F-72085 Le Mans 09, France

来源：

TETRAHEDRON-ASYMMETRY | 2008年 / 19卷 / 12期

关键词：

D O I：

10.1016/j.tetasy.2008.05.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New chiral beta-amino alcohols have been designed and synthesized from isosorbide, a by-product from the starch industry. These new ligands have been synthesized in three steps from isosorbide in good yields and have been used in asymmetric transfer hydrogenation reaction with Run complexes. One of these catalysts also demonstrated good catalytic activity and good enantioselectivity. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1450 / 1454

页数：5

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