Electrochemical production of sodium hypochlorite solutions for medical applications: Voltammetry of the platinum electrode in dilute chloride solutions

被引:0
|
作者
Grinberg, VA [1 ]
Skundin, AM [1 ]
Tuseeva, EK [1 ]
机构
[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 117071, Russia
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中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Kinetics of electrode processes are investigated on smooth platinum during the electrolysis of dilute chloride solutions. It is shown that oxygen and hypochlorite are adsorbed chemically on platinum in commensurate quantities, which grow linearly with the increasing potential. Hypochlorite itself oxidizes platinum surface, generating chemisorbed oxygen rather than an oxide phase.
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页码:1079 / 1082
页数:4
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