Preparation of chitosan based magnetic nanocomposite for tetracycline adsorption: Kinetic and thermodynamic studies

In the present study, the magnetic nanocomposite is fabricated using chitosan, thiobarbituric acid, malondialdehyde and Fe3O4 nanoparticles (CTM@Fe3O4). The fabricated nanocomposite (CTM@Fe3O4) is characterized using FTIR, TGA, BET, XRD, Raman, XPS, FESEM, and HRTEM techniques. The results of BET analysis confirmed that the nanocomposite has a mesoporous structure with high surface area of 376 m(2)g(-1), and high pore volume 0.3828 cm(3) g(-1). The adsorption of tetracycline (TC) onto CIM@Fe3O4 adsorbent is carried out using batch technique by changing several factors such as pH, concentration, contact time, and temperature. Langmuir and pseudo-second-order nonlinear models were found to be the best-fit models to predict isotherms and kinetics of adsorption, respectively. The highest adsorption capacity of 215.31mg/g was achieved at the optimum conditions of 0.05g adsorbent dosage, 60mg/L TC concentration. Overall, results demonstrated that CTM@Fe3O4 nanocomposite was an excellent adsorbent material with superparamagnetic properties, which allowed the separation as well as recovery of the adsorbent from aqueous solution using external magnet for effective industrial applications. (C) 2020 Elsevier B.V. All rights reserved.