Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

被引：90
|
作者：
Moebs-Sanchez, Sylvie [1 ]
Bouhadir, Ghenwa [1 ]
Saffon, Nathalie [3 ]
Maron, Laurent [2 ]
Bourissou, Didier [1 ]
机构：
[1] Univ Toulouse 3, Lab Heterochim Fdn & Appl, CNRS,UMR 5069, Equipe Ligands Bifonctionnels & Polymeres Biodegr, F-31062 Toulouse 9, France
[2] Univ Toulouse 3, INSA, Lab Phys & Chim Nanoobjets, UMR 5215, F-31077 Toulouse, France
[3] Univ Toulouse 3, FR 2599, F-31062 Toulouse 9, France
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 29期
关键词：
D O I：
10.1039/b805161e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ambiphilic phosphino-borane i-Pr2P(o-C6H4)BMes(2) affords stable versions of key zwitterionic intermediates by reactions with diethyl azodicarboxylate or PhNCO.
引用
收藏
页码：3435 / 3437
页数：3
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