The study of multi-walled carbon nanotubes with different diameter as anodes for lithium-ion batteries

被引：24
|
作者：
Zhang, Yanping [1 ]
Chen, Taiqiang [2 ]
Wang, Jinhe [1 ]
Min, Guoquan [1 ]
Pan, Likun [2 ]
Song, Zhitang [3 ]
Sun, Zhuo [2 ]
Zhou, Weimin [1 ]
Zhang, Jing [1 ]
机构：
[1] SNPC, Shanghai 200237, Peoples R China
[2] E China Normal Univ, Dept Phys, Minist Educ, Engn Res Ctr Nanophoton & Adv Instrument, Shanghai 200062, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, Lab Nanotechnol, Shanghai 200050, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2012年 / 258卷 / 10期
基金：
上海市自然科学基金;
关键词：
Multi-walled carbon nanotubes; Lithium-ion batteries; Anode; ELECTROCHEMICAL PERFORMANCE; CATHODE MATERIALS; FIELD-EMISSION; COMPOSITES; NANORODS; LIFEPO4; GROWTH;
D O I：
10.1016/j.apsusc.2012.01.067
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Multi-walled carbon nanotubes (MWCNTs) with different diameter range are employed as the anode materials in lithium-ion batteries (LIBs). The influence of diameter and pore structure on the electrochemical behavior of MWCNTs has been investigated by characterization of morphology and structure, nitrogen adsorption and desorption measurement, charge/discharge tests, and electrochemical impedance spectroscopy (EIS). The results show that MWCNTs with a diameter of 40-60 nm display the highest specific capacity (187.4 mAh g(-1) at the charge/discharge rate of 50 mA g(-1)) and good cyclability (101.9% Coulomb efficiency after 50 cycles). The excellent electrochemical performance verifies the feasibility of MWCNTs as a promising candidate for the anode of LIBs. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：4729 / 4732
页数：4
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