A new phosphonium calix[4]arene for selective anion recognition: Synthesis and studies in solution and in ion selective electrodes

被引：16
|
作者：
Pomecko, Radoslaw [1 ,2 ]
Asfari, Zouhair [1 ]
Hubscher-Bruder, Veronique [1 ]
Bochenska, Maria [2 ]
Arnaud-Neu, Francoise [1 ]
机构：
[1] CNRS, ULP, IPHC, DSA, F-67087 Strasbourg, France
[2] Gdansk Univ Technol, Fac Chem, Dept Chem Technol, PL-80264 Gdansk, Poland
来源：
SUPRAMOLECULAR CHEMISTRY | 2007年 / 19卷 / 07期
关键词：
calix[4]arene; perchlorate; phosphonium group; anion complexation; ISE;
D O I：
10.1080/10610270601123995
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of a new tetra (triphenylphosphonium) p-tert-butylcalix[4]arene 2 is presented. Its interactions with anions were studied by H-1 and P-31 NMR and UV absorption spectrophotometry, showing the biggest interaction with ClO4-, I- and SCN-. Anion selectivity in ion-selective PVC-membrane electrodes (ISEs) plasticized with o-NPOE containing ionophore 2 was also investigated. Compound 2 shows a potentiometric response for various anions with the following selectivity pattern: ClO4- > SCN- > I- > Cr2O72- > NO3- > Br- > Cl-.
引用
收藏
页码：459 / 466
页数：8
相关论文
共 50 条
  • [1] A novel calix[4]arene fluorescent receptor for selective recognition of acetate anion
    Miao, R
    Zheng, QY
    Chen, CF
    Huang, ZT
    [J]. TETRAHEDRON LETTERS, 2005, 46 (12) : 2155 - 2158
  • [2] A new carboxylate anion selective cobaltocenium calix[4]arene receptor
    Beer, PD
    Drew, MGB
    Hesek, D
    Nam, KC
    [J]. CHEMICAL COMMUNICATIONS, 1997, (01) : 107 - 108
  • [3] Cesium-ion selective electrodes based on calix[4]arene dibenzocrown ethers
    Kim, JS
    Ohki, A
    Ueki, R
    Ishizuka, T
    Shimotashiro, T
    Maeda, S
    [J]. TALANTA, 1999, 48 (03) : 705 - 710
  • [4] Anion recognition by phosphonium calix[4]arenes: synthesis and physico-chemical studies
    Pomecko, Radoslaw
    Asfari, Zouhair
    Hubscher-Bruder, Veronique
    Bochenska, Maria
    Arnaud-Neu, Francoise
    [J]. SUPRAMOLECULAR CHEMISTRY, 2010, 22 (05) : 275 - 288
  • [5] Synthesis of a new cesium selective calix[4]arene based chromoionophore
    Arora, V
    Chawla, HM
    Francis, T
    Nanda, M
    Singh, SP
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2003, 42 (12): : 3041 - 3043
  • [6] Silver ion-selective electrodes based on novel containing benzothiazolyl calix[4]arene
    Chen, LX
    Ju, HF
    Zeng, XS
    He, XW
    Zhang, ZZ
    [J]. ANALYTICA CHIMICA ACTA, 2001, 437 (02) : 191 - 197
  • [7] Polymeric membrane sodium ion-selective electrodes based on calix[4]arene triesters
    Kim, YD
    Jeong, H
    Kang, SO
    Nam, KC
    Jeon, S
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2001, 22 (04) : 405 - 408
  • [8] Selective anion recognition by a novel bis(calix[4]arene) ruthenium(II) bipyridyl receptor molecule
    Beer, PD
    Shade, M
    [J]. GAZZETTA CHIMICA ITALIANA, 1997, 127 (11): : 651 - 652
  • [9] SELECTIVE NITRATION OF CALIX[4]ARENE
    NAM, KC
    KIM, DS
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1994, 15 (04) : 284 - 286
  • [10] Synthesis of a tweezer-like bis(phenylthiapropoxy)calix[4]arene as a cation/π enhanced sensor for ion-selective electrodes
    Sun, H
    Zeng, XS
    Lü, JQ
    Leng, XB
    Chen, QF
    Xu, FB
    Li, QS
    He, XW
    Zhang, WQ
    Zhang, ZZ
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2002, 20 (10) : 1109 - 1114
12345