Supramolecular Architectures of Polyoxometalate Hybrids Originating from Halogen and Hydrogen-Bonding Interactions

被引：7
|
作者：
Lin, Xinjun [1 ]
Huang, Bo [1 ]
Xiong, Zhelun [1 ]
Fang, Ting [1 ]
Zhang, Xiaoxiao [1 ]
Xiao, Zicheng [1 ]
Wu, Pingfan [1 ]
机构：
[1] Hubei Univ Technol, Sch Mat & Chem Engn, Hubei Prov Key Lab Green Mat Light Ind, Inst POM Based Mat, Wuhan 430068, Hubei, Peoples R China
来源：
CHEMISTRYSELECT | 2018年 / 3卷 / 39期
基金：
中国国家自然科学基金;
关键词：
DESIGN; POLYMERS; DRIVEN;
D O I：
10.1002/slct.201802912
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper, we explored the possibility of building halogen bonds between polyoxometalate anions by synthesizing a series of polyoxometalate clusters covalently linked to different halogen atoms. Among these samples, the polyoxometalate hybrids containing bromide and iodine atoms exhibited both halogen and hydrogen bonding interactions between the hybrid anions, leading to novel 3D framework assemblies.
引用
收藏
页码：11008 / 11011
页数：4
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