Monometallic Ln3+ and heterometallic Ln3+-Cd2+complexes based on pentafluorophenylacetic acid: efficient control of dimension and luminescent properties

被引：7

作者：

Belousov, Y. A. ^{[1
,2
]}

Kiskin, M. A. ^{[3
]}

Sidoruk, A., V ^{[1
]}

Varaksina, E. A. ^{[2
]}

Shmelev, M. A. ^{[3
]}

Gogoleva, N., V ^{[3
]}

Taydakov, I., V ^{[2
,4
]}

Eremenko, I. L. ^{[3
]}

机构：

[1] Moscow MV Lomonosov State Univ, Chem Dept, Moscow 119991, Russia

[2] Russian Acad Sci, PN Lebedev Phys Inst, Moscow 119991, Russia

[3] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[4] GV Plekhanov Russian Univ Econ, Moscow 117997, Russia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2022年 / 75卷 / 09期

基金：

俄罗斯科学基金会; 俄罗斯基础研究基金会;

关键词：

cadmium; carboxylates; carboxylic acids; crystal structure; europium; lanthanides; luminescence; MOF; terbium; LANTHANIDE COORDINATION POLYMERS; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; PART I; COMPLEXES; FLUORESCENCE; CARBOXYLATES; LIGAND; SENSOR; IONS;

D O I：

10.1071/CH21333

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four new complexes [Ln(pfaa)(3)(H2O)(2)](n) (Ln = Eu (1), Tb (2)) and [Ln(2)Cd(2)(pfaa)(10) (phen)2(EtOH)(2)]center dot 2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent 1D coordination polymer, while the isostructural complexes 3 and 4 are molecular compounds. Complexes 1-4 show strong lanthanide-centred luminescence, since the introduction of phenanthroline leads to a significant increase in the observed lifetime (tau(obs)) and photoluminescent quantum yield.

引用

页码：572 / 580

页数：9

共 50 条

[1] Adjustment of coordination environment of Ln3+ ions to modulate near-infrared luminescent properties of Ln3+ complexes
Hui, Yani
Feng, Weixu
Wei, Tao
Lue, Xingqiang
Song, Jirong
Zhao, Shunsheng
Wong, Wai-Kwok
Jones, Richard A.
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (01) : 200 - 204
[2] Luminescent Properties of NaGdF4: Ln3+ (Ln3+ = Ce3+, Tb3+) Phosphors
Cao, Chunyan
Guo, Siling
Wu, Aijin
Lu, Guojun
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2014, 14 (05) : 3735 - 3738
[3] Synthesis and luminescent properties of Ln3+ (Ln3+ = Eu3+, Dy3+) -doped Bi2ZnB2O7 phosphors
Zhang Qiuhong
Wang Jing
Ni Haiyong
Wang Lingli
RARE METALS, 2012, 31 (01) : 35 - 38
[4] Synthesis and luminescent properties of Ln3+ (Ln3+ = Eu3+, Dy3+) -doped Bi2ZnB2O7 phosphors
Qiuhong Zhang
Jing Wang
Haiyong Ni
Lingli Wang
Rare Metals, 2012, 31 : 35 - 38
[5] Synthesis and luminescent properties of ellipsoid-like YBO3:Ln3+ (Ln = Eu, Tb)
Leng, Zhihua
Liu, Lu
Li, Linlin
Gan, Shucai
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2014, 463 : 1 - 7
[6] Synthesis and luminescent properties of Ln3+ (Ln3+=Eu3+,Dy3+)-doped Bi2ZnB2O7 phosphors
ZHANG Qiuhonga
RareMetals, 2012, 31 (01) : 35 - 38
[7] Nature of the magnetic interaction in the (Cu2+, Ln3+) pairs: an empirical approach based on the comparison between homologous (Cu2+, Ln3+) and (NiLS2+, Ln3+) complexes
Chem Eur J, 9 (1616-1620):
[8] Nature of the magnetic interaction in the (Cu2+, Ln3+) pairs:: An empirical approach based on the comparison between homologous (Cu2+, Ln3+) and (NiLS2+, Ln3+) complexes
Costes, JP
Dahan, F
Dupuis, A
Laurent, JP
CHEMISTRY-A EUROPEAN JOURNAL, 1998, 4 (09) : 1616 - 1620
[9] Fabrication and luminescent properties of CaWO4:Ln3+ (Ln = Eu, Sm, Dy) nanocrystals
Wenxin Wang
Piaoping Yang
Shili Gai
Na Niu
Fei He
Jun Lin
Journal of Nanoparticle Research, 2010, 12 : 2295 - 2305
[10] GdVO4:Ln3+ (Ln = Eu, Dy, and Sm) microstructures: solvothermal and luminescent properties
Zheng, Fuhou
Wang, Wenxin
Yang, Piaoping
OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2011, 5 (5-6): : 596 - 599

← 1 2 3 4 5 →