Preparation of polyvinyl alcohol-chitosan-NH4Br catalyst and its application to cycloaddition of carbon dioxide to propylene oxide

被引:3
|
作者
Kim, Hak-Min [1 ]
Oh, Kyeongseok [2 ]
Kyung, Daeseung [3 ]
Ahn, Han-geun [4 ]
Yoon, Inhwan [5 ]
Kwak, Soonjong [6 ]
Nah, In Wook [7 ]
机构
[1] Changwon Natl Univ, Ind Technol Res Ctr, Changwon Si, South Korea
[2] Inha Tech Coll, Dept Chem & Environm Technol, Incheon, South Korea
[3] Univ Ulsan, Sch Civil & Environm Engn, Daehak Ro 93, Ulsan 44610, South Korea
[4] Korea Land & Housing Corp, Urban Infrastruct Off, Jinju Si, South Korea
[5] Land & Housing Inst, Future Strategy Res Dept, Daejeon, South Korea
[6] Korea Inst Sci & Technol, Ctr Photoelect Hybrids Res, Seoul, South Korea
[7] Korea Inst Sci & Technol, Ctr Environm Hlth & Welf Res, Hwarangno 14 Gil 5, Seoul 02792, South Korea
来源
CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 2022年 / 100卷 / 08期
关键词
cycloaddition reaction; functional group; NH4Br; propylene oxide; PVA-chitosan; BIOPOLYMER-SUPPORTED CATALYST; CYCLIC CARBONATES; IONIC LIQUID; QUATERNIZED CHITOSAN; POLYMER ELECTROLYTE; CO2; EPOXIDES; EFFICIENT; MEMBRANES; FIXATION;
D O I
10.1002/cjce.24275
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
An eco-friendly polyvinyl alcohol (PVA)-chitosan(CS)-NH4Br catalyst was prepared using a modified solution method. Although the amounts of PVA and CS were fixed, the amount of NH4Br was varied in the range 15-45 wt.%. The catalytic performance of PVA-CS-NH4Br was compared based on the carbonation performance in the presence of single-component catalysts (PVA, CS, and NH4Br) and dual component catalyst (PVA-CS). The catalytic activity of PVA-CS was inadequate and considerably less than that observed when either PVA or CS was exclusively loaded. The number of functional groups within the PVA-CS structure was presumed to have been reduced due to the interactions of the OH groups in PVA and CS. However, the PVA-CS-NH4Br catalyst distinctively exhibited its catalytic performance. It has been suggested that NH4Br aided in sustaining the innate functional groups that both PVA and CS have within the PVA-CS-NH4Br structure. These results indicate that the functional groups and nucleophiles within the PVA-CS-NH4Br structure more effectively participated in the carbonation of propylene oxide. Quantitatively, the addition of 30 wt.% NH4Br yielded the best performance. Characteristic analyses of the catalysts were performed using X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.
引用
收藏
页码:1755 / 1763
页数:9
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