Concise synthesis of biologically interesting mollugin and its analogues

被引:0
|
作者
Lee, Yong Rok [1 ]
Wang, Xue [1 ]
Kim, Yun Mi [1 ]
Shim, Jae Jin [1 ]
Kim, Byung Nam [1 ]
Han, Do Hung [1 ]
机构
[1] Yeungnam Univ, Sch Chem Engn & Technol, Kyongsan 712749, South Korea
关键词
mollugin; 3,4-dihydromollugin; electrocyclization; PhB(OH)(2)/AcOH;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of naturally occurring mollugin and its analogues, 3,4-dihydromollugin, cis-3,4-dihydroxy-3,4-dihydromollugin, and trans-3,4-dihydroxy-3,4-dihydromollugin was achieved starting from 1,4-dihydroxynaphthalene-2-carboxylic acid. The key reaction is an electrocyclization for pyranyl ring formation in the presence of PhB(OH)(2)/AcOH.
引用
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页码:1735 / 1738
页数:4
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