Vibrational Properties of Silver-doped Arsenic Chalcogenide Bulk Glasses

被引:0
|
作者
Hasapis, Th. Ch. [1 ]
Andrikopoulos, K. S. [2 ]
Hatzikraniotis, E. [1 ]
Dracopoulos, V. [3 ]
Wagner, T. [4 ]
Yannopoulos, S. N. [3 ]
Paraskevopoulos, K. M. [1 ]
机构
[1] AU Th, Dept Phys, Thessaloniki 54124, Greece
[2] AU Th, Sch Technol, Div Phys, Thessaloniki 54124, Greece
[3] FORTH ICE HT, GR-26504 Patras, Greece
[4] Univ Pardubice, Dept Inorgan Chem, Pardubice 53210, Czech Republic
关键词
Chalcogenide glasses; phase separation; vibrational spectroscopy; effective medium theory; OPTICAL-PROPERTIES; PHASE-SEPARATION;
D O I
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中图分类号
O59 [应用物理学];
学科分类号
摘要
Silver-doped As33S67 and As33S33Se33 bulk glasses studied by means of Scanning Electron Microscopy (SEM) and infrared reflectivity, exhibit two-phase glasses, for a wide range of Ag concentration. Using the Effective Medium Approximation we show that the structure is actually a proper average of two components, a Ag-poor and a Ag-rich glass phase. The dominant structural unit in both phases is the pyramidal units AsX3/2 units The latter are arranged in different medium-range order motifs A detailed analysis of the reflectivity and absorption coefficient spectra made it possible to elucidate the short and medium range structural order for the Ag-poor and Ag-rich phases
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页码:283 / +
页数:2
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