Derivatives of the fluorite Type:: [Fe(NH3)6][TaF6]2 and [Ni(NH3)6][TaF6]2

被引：0
|
作者：
Schoning, RA [1 ]
Meyer, G [1 ]
机构：
[1] Univ Koln, Inst Anorgan Chem, D-50939 Koln, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 09期
关键词：
crystal structure; fluorite-type derivatives; iron(II) ammoniate; nickel(II) ammoniate; hexafluorotantalates(V);
D O I：
10.1002/(SICI)1521-3749(199809)624:9<1389::AID-ZAAC1389>3.0.CO;2-A
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Light blue single crystals of [Fe(NH3)(6)][TaF6](2) and [Ni(NH3)(6)][TaF6](2) are obtained from 36:1:6 molar mixtures of (NH4)F, iron/nickel and tantalum powders, respectively, in sealed Monel metal ampoules at 400 degrees C. They both crystallize isotypic with [CO(NH3)(6)][PF6](2) (cubic, Fm-3m, Z = 4, a = 1259.0(2)/1260.4(2) pm) in a structure that can be derived from the basic fluorite-type of structure according to [Ca][F](2)=[Fe(NH3)(6)] [TaF6](2), for example.
引用
收藏
页码：1389 / 1390
页数：2
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