Synthesis and crystal structure of the novel trimanganese tetrathiolate incomplete cubane:: [Mo(η5-C5H5)2(H)CO][Mn3(CO)9(μ-SC6H5)4]

被引：4

作者：

Dias, AR

Galvao, A

Garcia, MH

de Brito, MJV

机构：

[1] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[2] Univ Lisbon, Fac Ciencias, DQB, P-1749016 Lisbon, Portugal

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 620卷 / 1-2期

关键词：

trinuclear; manganese incomplete cubane; thiolate-bridged; molybdenum biscyclopentadienyl; carbonyl; hydride;

D O I：

10.1016/S0022-328X(00)00798-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unexpected trimanganese(I) tetrathiolate-bridged complex, [Mn-3(CO)(9)(mu -SC6H5)(4)](-), with an incomplete cubane structure, was obtained by thermal reaction of [Mn-2(CO)(10)] with [Mo(eta (5)-C5H5)(2)(SC6H5)(2)]. The structure, established by single-crystal X-ray diffraction studies, shows the cation, [Mo(eta (5)-C(5)H5)(2)(H)CO](+), directed towards the vacant site of the cubane structure. Possible routes by which the anion and the cation could be formed are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：276 / 281

页数：6

共 50 条

[1] SYNTHESIS AND CRYSTAL STRUCTURE OF DINUCLEAR IRON CARBONYL DERIVATIVE （μ-SC6H5） (μ-P （SC6H5）2) Fe2 （CO）5 (P-（SC6H5）3)
Wu Bin-Fang Su Han-Quan Yan Xiu-Ying Hu Xing Liu Qi-WangFuzhou Laboratory of Structural Chemistry
结构化学, 1992, (05) : 339 - 342
[2] Monocyclopentadienyltitanium complexes with thiolate ligands;: crystal structure of Ti(η5-C5H5)(SC6H5)3
Lindsell, WE
Rosair, GM
Spence, MA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 577 (01) : 9 - 14
[3] THE ELECTRONIC-STRUCTURES OF [(C5H4-C6H5)CR(CO)3]-, [(C6H4COC6H5)CR(CO)3)-, [(C5H4CH2C6H5)CR(CO)3]-, [(C5H4C2H2C6H5)CR(CO)3]- AND (C6H5-C5H4)MN(CO)3, (C6H5COC5H4)MN(CO)3, (C6H5CH2C5H4)MN(CO)3, (C6H5C2H2C5H4)MN(CO)3
FITZPATRICK, NJ
GOGAN, NJ
SAYAL, PK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 301 (02) : C31 - C34
[4] Decamethylpentasilacycloheptyne • Mo2(CO)4(η5-C5H5)2 and cycloheptyne • Mo2(CO)4(η5-C5H5)2
Cervantes-Lee, F
Parkanyi, L
Kapoor, RN
Mayr, AJ
Pannell, KH
Pang, Y
Barton, TJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 562 (01) : 29 - 33
[5] CRYSTAL STRUCTURE OF FeaTe2（CO）6（NO）(η5-C5H5)
Yang Xiaoguang Huang Jinshun and Huang JinlingFujian Institute of Research on the Structure of Matter
结构化学, 1985, (02) : 136 - 138
[6] ELECTROCHEMISTRY OF THE COMPLEXES [(C2H5)4N]2MN(SC6H5)4, [(C2H5)4N]4N2FE(SC6H5)4, [(C2H5)4N]2CO(SC6H5)4, [(C2H5)4N]2NI(SC6H5)4
FABRE, PL
POILBLANC, R
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1986, (05): : 740 - 744
[7] Synthesis and structure of the cubane type [Fe2Sb(CO)5(η5-C5H5)]4 cluster
Konchenko, SN
Virovets, AV
Apenina, SA
Tkachev, SV
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (11) : 555 - 557
[8] Synthesis, structure, and redox properties of [{(η5-C5H5)Co(S2C6H4)}2Mo(CO)2], a novel metalladithiolene cluster
Nihei, M
Nankawa, T
Kurihara, M
Nishihara, H
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1999, 38 (08) : 1098 - 1100
[9] New studies on the chemical oxidation of bis(η5-cyclopentadienyl)dithiolatemolybdenum(IV) complexes.: Crystal structures of [(Mo(η5-C5H5)2S(C6H4-o-S)C6H5)][BF4] and [Mo(η5-C5H5)2(SC6H5)2]
Dias, AR
Garcia, MH
de Piedade, MFM
Carrondo, MAAFD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 632 (1-2) : 107 - 112
[10] STRUCTURAL STUDIES OF (ETA-5-C5H5)2NB(SC6H5)2, [(ETA-5-C5H5)2NB(SC6H5)2+], AND [(ETA-5-C5H5)2NB(MU-SC6H5)2MO(CO)4+]
DARENSBOURG, MY
SILVA, R
REIBENSPIES, J
PROUT, CK
ORGANOMETALLICS, 1989, 8 (05) : 1315 - 1323

← 1 2 3 4 5 →