Reaction of N-arylsulfonyl-p-quinonimines and semiquinoid compounds derived therefrom with arylsulfinic acids

被引：1

作者：

Avdeenko, AP ^{[1
]}

Zhukova, SA ^{[1
]}

Menafova, YV ^{[1
]}

Yusina, AL ^{[1
]}

机构：

[1] Donbass State Machinebldg Acad, UA-184313 Kramatorsk, Ukraine

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 36卷 / 06期

关键词：

D O I：

10.1007/BF02757435

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Arylsulfonyl-2,3,5,6-tetrachloro-1,4-benzoquinonimines and 4-arylsulfonylimino-2,3,5,6,6-pentachloro-2-cyclohexen-1-ones react with arylsulfinic acids regioselectively along 6,1-addition. With 4-arylsulfonylimino-2,3,5,6,6-pentachloro-2-cyclohexen-1-ones the 6,1 addition is preceded by nucleophilic substitution of chlorine in position 2. With N-arylsulfonyl-2,3-dichloro-1,4-naphthoquinonimines, 4-arylsulfonyl-2,2,3-trichloro- 1,2,3,4-tetrahydronaphthalen-1-ones and 4-arylsulfonyl-2,2,3,3-tetrachloro-1,2,3,4-tetrahydronaphthalen-1-ones occurred nucleophilic substitution of chlorine in position 2 followed by 6,1-addition of arylsulfinic acid molecule.

引用

页码：808 / 812

页数：5

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