A new crystalline phase related to an Al-Ni-Co decagonal phase

被引:15
|
作者
Hiraga, K [1 ]
Ohsuna, T [1 ]
Nishimura, S [1 ]
机构
[1] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
关键词
quasicrystal; decagonal quasicrystal; crystalline approximant; AI-Ni-Co; transmission electron microscopy;
D O I
10.1016/S0925-8388(01)01364-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new crystalline phase (called 'W-(AlNiCo) phase'), which is closely related to Al-Ni-Co decagonal quasicrystals with 0.4 nm and 0.8 nm periodicity, has been found in an Al72.5Ni7.5Co20 alloy annealed at 950 degreesC. The W-(AlNiCo) phase has a monoclinic structure with lattice parameters a=3.99 nm, b=0.82 nm, c=2.36 nm and beta =90 degrees, and the space group of Cm (No. 8). Structural characteristics of the W-(AlNiCo) phase and the resemblance to those of an Al-Ni-Co pentagonal quasicrystal are discussed from atom-scale observations using high-angle annular detector dark-held scanning transmission electron microscopy and high-resolution electron transmission microscopy. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:145 / 150
页数:6
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