Conformational characteristics and configurational properties of poly(ethylene succinate) and poly(butylene succinate) and structure-property-function relationships of representative biodegradable polyesters

被引：20
|
作者：
Sasanuma, Yuji [1 ]
Nonaka, Yuta
Yamaguchi, Yuki
机构：
[1] Chiba Univ, Grad Sch, Dept Appl Chem & Biotechnol, Inage Ku, Chiba 2638522, Japan
来源：
POLYMER | 2015年 / 56卷
基金：
日本学术振兴会;
关键词：
Poly(ethylene succinate); Poly(butylene succinate); Conformational analysis; COUPLING-CONSTANTS; CRYSTAL-STRUCTURES; MELTING BEHAVIOR; CRYSTALLIZATION; DEGRADATION; POLY(L-LACTIDE); TEREPHTHALATE); POLYETHERS; SURFACES; EQUATION;
D O I：
10.1016/j.polymer.2014.11.003
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Conformational characteristics and configurational properties of synthetic biodegradable polyesters, poly(ethylene succinate) and poly(butylene succinate), have been investigated by NMR experiments and molecular orbital calculations on their model compounds and the rotational isomeric state calculations for the two aliphatic polyesters. The results have been related to their crystal structures and thermal properties and compared with those obtained previously for poly((R)-3-hydroxybutyrate) and poly(lactic acid) to elucidate structure property relationships of the representative biodegradable polyesters. In addition, selective affinities to degradative enzymes of the four polyesters have been satisfactorily explained in terms of their conformational characteristics and interactions with the depolymerases. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：327 / 339
页数：13
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