Conductive substrates-based component tailoring via thermal conversion of metal organic framework for enhanced microwave absorption performances

被引:33
|
作者
Huang, Xiaogu [1 ]
Ma, Yabin [1 ]
Lai, Haoran [2 ]
Jia, Qi [3 ]
Zhu, Liyan [3 ]
Liu, Jun [3 ]
Quan, Bin [1 ]
机构
[1] Nanjing Univ Informat Sci & Technol, Sch Chem & Mat Sci, Nanjing 210044, Peoples R China
[2] Univ Elect Sci & Technol China, Yangtze Delta Reg Inst Huzhou, Huzhou 313001, Peoples R China
[3] Army Engn Univ PLA, Coll Field Engn, Nanjing 210094, Peoples R China
基金
中国博士后科学基金;
关键词
Fe-MOF; rGO; Synergistic effect; Microwave absorption; Broad-band absorption; ELECTROMAGNETIC-WAVE ABSORPTION; MICROSPHERES; FE3O4; NANOCOMPOSITES; CONSTRUCTION; EFFICIENT; NANORODS;
D O I
10.1016/j.jcis.2021.10.137
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Component tailoring, especially for the conductive substrates-based composites, acts as a significant role in optimizing the electromagnetic (EM) parameters and improving the EM response capability. Here, Febased metal oxides modified rGO microwave absorbers with component evolution were fabricated through hydrothermal treatment and subsequent pyrolysis process. The synergistic effects of the dielectric loss (multi-relaxations) and the magnetic loss (resonance and eddy current) are found to be effective in promoting the microwave absorption property of Fex-1Ox/C/rGO absorbers. As the thermal treatment temperature reaches 500 degrees C, the as-prepared composite sample shows ideal microwave absorption performance, where the reflection loss value is -25.94 dB, and the effective bandwidth reaches 5.84 GHz at 1.9 mm. In addition, CST simulation was employed to analyze the microwave absorption capability in the actual far field. When the scattering angle is 0 degrees and 20 degrees, the radar cross section (RCS) reduction of S-500/ PEC layers is 8.11 dB m2 and 8.80 dB m2, respectively. This study exhibits the importance of component tailoring in enhancing the performances of substrates-based microwave absorption materials. (c) 2021 Elsevier Inc. All rights reserved.
引用
收藏
页码:1323 / 1333
页数:11
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