LST-GDC composite anode on LaGaO3-based solid oxide fuel cell

被引:54
|
作者
Yoo, Kyung Bin
Choi, Gyeong Man [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Fuel Cell Res Ctr, Pohang 790784, South Korea
关键词
SOFC; Anode; Polarization resistance; Perovskite; Impregnation; LANTHANUM GALLATE ELECTROLYTE; DOPED STRONTIUM-TITANATE; DIRECT OXIDATION; SOFC ANODES; PERFORMANCE; TEMPERATURE; SRTIO3;
D O I
10.1016/j.ssi.2010.06.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
La-doped SrTiO3 (LST, La0.2Sr0.8TiO3) is a candidate as an anode material to solve the problem of Ni-based anode in LaGaO3-based SOFC. LST-Gd0.2Ce0.8O2-delta (GDC) anodes of various composition ratios were evaluated in order to optimize the performance of composite anode on LaGaO3-based solid oxide fuel cell. Electrochemical impedance spectra (EIS) indicated that the addition of GDC into LST significantly reduces the anode polarization thus leading to an increased performance. LST30-GDC70 (LST:GDC = 30:70 wt.%) composite anode showed the lowest polarization-resistance value at 800 degrees C. With further Ni impregnation into anode, the maximum power density of the single cell was similar to 0.3 W/cm(2) at 800 degrees C in air/97% H-2 + 3% H2O gas. The result demonstrated the potential use of LST-GDC as a SOFC anode. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:515 / 518
页数:4
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