An alternative method for the highly selective iodination of alcohols using a CsI/BF3•Et2O system

被引:12
|
作者
Hayat, S [1 ]
Atta-ur-Rahman [1 ]
Khan, KM [1 ]
Choudhary, MI [1 ]
Maharvi, GM [1 ]
Zia-Ullah [1 ]
Bayer, E [1 ]
机构
[1] Univ Karachi, HEJ Res Inst Chem, Int Ctr Chem Sci, Karachi 75270, Pakistan
关键词
D O I
10.1081/SCC-120021844
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of allylic and benzylic alcohols have been converted into the corresponding iodides using cesium iodide (CsI) in the presence of boron trifluoride etherate (BF3.Et2O) in acetonitrile under mild conditions.
引用
收藏
页码:2531 / 2540
页数:10
相关论文
共 50 条
  • [1] An expedient and highly selective iodination of alcohols using a KI/BF3•Et2O system
    Bandgar, BP
    Sadavarte, VS
    Uppalla, LS
    TETRAHEDRON LETTERS, 2001, 42 (05) : 951 - 953
  • [2] BF3•Et2O Promoted Sulfuration of Steroidal Sapogenins
    Wang, Jun
    Wu, Jingjing
    Tian, Weisheng
    CHINESE JOURNAL OF CHEMISTRY, 2015, 33 (06) : 632 - 636
  • [3] Application of TFA and BF3•Et2O in the synthesis of dithiaporphyrins
    Zhu Yan
    Zhu Yi-Zhou
    Zhang Jing-Ming
    Zheng Jian-Yu
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2008, 29 (09): : 1760 - 1764
  • [4] Electrosynthesis of highly conducting poly(1,5-dihydroxynaphthalene) in BF3•Et2O
    Lu, Baoyang
    Zeng, Liqiang
    Xu, Jingkun
    Le, Zhanggao
    Rao, Huoyu
    EUROPEAN POLYMER JOURNAL, 2009, 45 (08) : 2279 - 2287
  • [5] BF3•Et2O catalyzed allylation of oxindoles with allyl trichloroacetimidate
    Ma, Jiao
    Zhou, Ling
    Chen, Jie
    TETRAHEDRON LETTERS, 2015, 56 (12) : 1501 - 1504
  • [6] Application of BF3•Et2O in the synthesis of cyclic organic peroxides
    Radulov, Peter S.
    Yaremenko, Ivan A.
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2020, 56 (09) : 1146 - 1148
  • [7] Role of temperature in [3+2]-cycloaddition of isoselenocyanates with oxiranes using BF3•Et2O
    Sengoden, Mani
    Punniyamurthy, Tharmalingam
    RSC ADVANCES, 2012, 2 (07): : 2736 - 2738
  • [8] Regioselective reduction of 4,6-O-benzylidenes using triethylsilane and BF3•Et2O
    Debenham, SD
    Toone, EJ
    TETRAHEDRON-ASYMMETRY, 2000, 11 (02) : 385 - 387
  • [9] Selective synthesis of Neu5Ac2en and its oxazoline derivative using BF3•Et2O
    Morais, Gored Ribeiro
    Oliveira, Rudi Santiago
    Falconer, Robert A.
    TETRAHEDRON LETTERS, 2009, 50 (14) : 1642 - 1644
  • [10] Lactonization of 2-Alkynylbenzoates for the Assembly of lsochromenones Mediated by BF3•Et2O
    Zhang, Xiang
    Wan, Xintong
    Cong, Ying
    Zhen, Xiaohua
    Li, Qiao
    Zhang-Negrerie, Daisy
    Du, Yunfei
    Zhao, Kang
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (16): : 10402 - 10411