Tetraaquabis(4,4′-bipyridine)manganese(II) pyridine-2,6-dicarboxylate tetrahydrate

被引：2
|
作者：
Gao, Yu-Xiang [1 ]
Wang, Li-Bin [1 ]
Niu, Yan-Ling [1 ]
机构：
[1] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S160053680703766X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Mn(C10H8N2)(2)(H2O)(4)](C7H3NO4)center dot 4H(2)O, prepared by hydrothermal synthesis, is isostructural with its Fe-II analogue. The compound contains isolated tetraaquabis(4,4'-bipyridine) manganese(II) cations, with two 4,4'-bipyridine molecules bound to Mn-II in a trans manner. The cations lie in layers, with pyridine-2,6-dicarboxylate dianions and water molecules forming an extensive hydrogen-bond network between them. The cations exhibit noncrystallographic inversion symmetry. The crystal was a partial inversion twin.
引用
收藏
页码：M2283 / U342
页数：13
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