A new heteroleptic ruthenium sensitizer enhances the absorptivity of mesoporous titania film for a high efficiency dye-sensitized solar cell

被引:0
|
作者
Gao, Feifei [1 ]
Wang, Yuan [1 ]
Zhang, Jing [1 ]
Shi, Dong [1 ]
Wang, Mingkui [2 ]
Humphry-Baker, Robin [2 ]
Wang, Peng [1 ]
Zakeeruddin, Shaik M. [2 ]
Graetzel, Michael [2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Swiss Fed Inst Technol, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A heteroleptic polypyridyl ruthenium complex, cis-Ru(4,4'-bis(5-octylthieno[3,2-b]thiophen-2-yl)-2,2'-bipyridine)(4,4'-dicarboxyl-2,2'-bipyridine)(NCS) 2, with a high molar extinction coefficient of 20.5 x 10(3) M(-1) cm(-1) at 553 nm has been synthesized and demonstrated as a highly efficient sensitizer for a dye-sensitized solar cell, giving a power conversion efficiency of 10.53% measured under an irradiation of air mass 1.5 global ( AM 1.5G) full sunlight.
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页码:2635 / 2637
页数:3
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