Synthesis and double doping behavior of a poly(p-phenylenevinylene)s bearing conjugated side chains

被引：4
|
作者：
Kawashima, Hirotsugu [1 ]
Kawabata, Kohsuke [1 ]
Goto, Hiromasa [1 ]
机构：
[1] Univ Tsukuba, Inst Mat Sci, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058573, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2012年 / 50卷 / 08期
关键词：
atomic force microscopy (AFM); conjugated polymers; ESR; EPR; UV-vis spectroscopy; FIELD-EFFECT TRANSISTORS; LIGHT-EMITTING-DIODES; BAND-GAP; REGIOREGULAR POLYTHIOPHENES; SOLAR-CELLS; POLYMERS; COPOLYMERS; DERIVATIVES; VINYLENE)S; DESIGN;
D O I：
10.1002/pola.25919
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A poly(p-phenylenevinylene) derivative bearing conjugated side chains (polyCPV) was synthesized by Migita-Kosugi-Stille type coupling polycondensation reaction. This polymer contains phenylenevinylene units in both the main chain and the side chains. UVvis absorption and fluorescence emission spectroscopies revealed a well-developed p-conjugation of the polyCPV. The absorption band of the polymer was extended to long wavelengths. A fluorescent emission maximum of polyCPV is located at considerably longer wavelengths than that of the conjugated side chain monomer. Electron spin resonance measurements of polyCPV confirmed generation of charge species in both the main chain and the side chains via iodine doping. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
引用
收藏
页码：1530 / 1538
页数：9
相关论文
共 50 条
  • [1] Poly(p-phenylenevinylene) derivatives with conjugated thiophene side chains: Synthesis, photophysics and photovoltaics
    Shen, Ping
    Ding, Tianpeng
    Huang, Hui
    Zhao, Bin
    Tan, Songting
    SYNTHETIC METALS, 2010, 160 (11-12) : 1291 - 1298
  • [2] Synthesis and photovoltaic properties of poly(p-phenylenevinylene) derivatives with two triphenylamine and bithiophene conjugated side chains
    Shen, Ping
    Zhao, Bin
    Huang, Xianwei
    Huang, Hui
    Tan, Songting
    EUROPEAN POLYMER JOURNAL, 2009, 45 (09) : 2726 - 2731
  • [3] Synthesis and electrolumine scent property of poly (p-phenylenevinylene)s bearing triarylamine pendants
    Liang, F
    Pu, YJ
    Kurata, T
    Kido, J
    Nishide, H
    POLYMER, 2005, 46 (11) : 3767 - 3775
  • [4] Oxadiazole containing poly(p-phenylenevinylene)s: synthesis and characterization
    Li, Pengfei
    Wen, Shanpeng
    Cheng, Weidong
    Zhang, Jibo
    Yao, Shiyu
    Xu, Bin
    Tian, Wenjing
    NEW JOURNAL OF CHEMISTRY, 2012, 36 (08) : 1626 - 1633
  • [5] Synthesis and optical properties of poly(phenylenethiophene)s bearing conjugated side chains
    Kawashima, Hirotsugu
    Kawabata, Kohsuke
    Wang, Aohan
    Goto, Hiromasa
    DESIGNED MONOMERS AND POLYMERS, 2015, 18 (07) : 661 - 668
  • [6] Dye doping of poly(p-phenylenevinylene)s by vapor transportation for photovoltaic application
    Tanigaki, N
    Mochizuki, H
    Mo, XL
    Mizokuro, T
    Hiraga, T
    Taima, T
    Yase, K
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (1B): : 630 - 632
  • [7] CORRELATION ENERGIES CALCULATIONS FOR POLY (p-PHENYLENEVINYLENE) (PPV) CHAINS
    Zhao, Hua
    JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY, 2009, 8 (05): : 881 - 886
  • [8] Synthesis and characterization of an oligomeric conjugated metal-containing poly(p-phenylenevinylene) analogue
    Jiang, Jian
    Leung, Alfred C. W.
    MacLachlan, Mark J.
    DALTON TRANSACTIONS, 2010, 39 (28) : 6503 - 6508
  • [9] Novel Isoindigo-Based Conjugated Polyelectrolytes: Synthesis and Fluorescence Quenching Behavior with Water-Soluble Poly(p-Phenylenevinylene)s
    Kou, Chun
    He, Xiaolong
    Jiang, Xueyu
    Ni, Yifeng
    Liu, Ling
    Huangfu, Changxin
    Liu, Kuan
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2015, 53 (19) : 2223 - 2237
  • [10] Facile ADMET synthesis of silicon containing poly(p-phenylenevinylene)s
    Peetz, Ralf M.
    Mukherjee, Narayan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
12345