Picosecond time-resolved resonance Raman observation of Iso-CH2Br-I following A-band photodissociation of CH2BrI in the solution phase

被引：0
|
作者：
Kwok, WM
Ma, CS
Phillips, D
Parker, AW
Towrie, M
Matousek, P
Phillips, DL
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Rutherford Appleton Lab, CLRC, Cent Laser Facil, Didcot OX11 0QX, Oxon, England
[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2001年 / 341卷 / 3-4期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present picosecond time-resolved resonance Raman spectra that demonstrate formation of the iso-CH2Br-I species following A-band excitation of bromoiodomethane in cyclohexane solvent at room temperature. The isoCH(2)Br-I species is produced within several ps and appears to decay with a half-life on the 2-3 ns time scale. We compare these results to previous studies on solution phase photodissociation of dihalomethanes. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：292 / 298
页数：7
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