Palladium-catalysed asymmetric allylation and complex formation involving P,N-bidentate diamidophosphites with 1,3,2-diazaphospholidine cycles

被引：2
|
作者：
Gavrilov, KN
Tsarev, VN
Zheglov, SV
Lyubimov, SE
Shiryaev, AA
Davankov, VA
机构：
[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 119991, Russia
[2] Ryazan State Pedag Univ, Dept Chem, Ryazan 390000, Russia
来源：
INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
chiral P; N-ligands; diamidophosphites; palladium; rhodium; asymmetric allylation;
D O I：
10.1016/j.ica.2004.12.047
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New chiral P,N-bidentate 1,3,2-diazaphospholidine ligands were obtained by one-step phosphorylation of (2S,3S)-2-(ferroceny-lideneamino)-3-methylpentan-1-ol and (4S,5S)-(-)-2-methyl-4-hydroxymethyl-5-phenyt-2-oxazoline. Complexation of the new ligands with [Rh(CO)(2)Cl](2) and [Pd(allyl)Cl](2) was found to give chelate complexes [Rh(CO)Cl(eta(2)-P,N)] and [Pd(allyl) (eta(2)-P,N)]+BF4-, correspondingly. With the new P,N-ligands, up to 70% ee was achieved in the asymmetric Pd-catalysed sulfonylation of 1,3-diphenyl-2-propenyl acetate with sodium p-toluenesulfinate. In the enantioselective alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate, up to 91% enantioselectivity was achieved by using [Pd(allyl)(eta(2)-P, N)]+ BF4- complexes as chiral catalysts. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：2077 / 2081
页数：5
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