Effect of growth conditions on microstructure of sputtered precursor for CuIn1-xGaxSe2 (CIGS) absorber layer deposited on stainless steel substrates

被引:4
|
作者
Behr, M. [1 ]
Sharma, M. [1 ]
Sprague, S. [1 ]
Shinkel, N. [1 ]
Kerbleski, J. [1 ]
Alvey, C. [1 ]
Rozeveld, S. [1 ]
Hasan, T. [1 ]
Wintland, C. [1 ]
Mushrush, M. [1 ]
Wall, A. [1 ]
机构
[1] Dow Chem Co USA, Midland, MI 48674 USA
关键词
SOLAR-CELLS; CU(IN; GA)SE-2;
D O I
10.1016/j.tsf.2018.08.045
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, we report the effect of growth conditions on the properties of sputtered precursor thin films for CuIn1-xGaxSe2 (CIGS) absorber layers. Specifically, precursor films containing Cu, In, Ga, and Se were deposited via co-sputtering on flexible Mo-coated stainless steel substrates over a wide range of compositions and deposition conditions. The impact on precursor film phase, morphology, and elemental distribution was investigated as a function of precursor Se content, substrate temperature, target type (CIG/CIG vs. In/Cu3Ga), and Na content. Precursor films selenized at high temperature (> 500 degrees C) to form stoichiometric CIGS and completed using a CdS n-type buffer layer and transparent conducting oxide window layers exhibited full-cell efficiencies as high as 11.5%.
引用
收藏
页码:36 / 45
页数:10
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