Pseudorotaxanes and rotaxanes from macrocyclic rings incorporating acridinone, 9-phenylacridinium and 9-phenyl-9-methoxy-acridane moieties

被引：8

作者：

Orda-Zgadzaj, M. ^{[1
]}

Abraham, W. ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

TETRAHEDRON | 2008年 / 64卷 / 11期

关键词：

pseudorotaxane; acridane; acridinium; photochemistry;

D O I：

10.1016/j.tet.2007.12.054

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two novel crown ethers incorporating the acridinone and the 9-phenyl-9-methoxy-acridane unit were used to form pseudorotaxanes with the 1,2-bis(4,4'dipyridinium)ethane axle, which are stoppered by the alkylative method to form rotaxanes. The pseudorotaxane formed from the acridane-containing crown was photochemically converted to the corresponding acridinium methoxide thereby releasing the guest. The acridane-containing rotaxane could not be isolated because the preparation conditions formed the acridinium salt. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：2669 / 2676

页数：8

共 2 条

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