Visible-light-mediated oxidative arylation of vinylarenes under aerobic conditions

被引：40
|
作者：
Bu, Meijie [1 ]
Niu, Teng Fei [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Jiangsu, Peoples R China
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2015年 / 5卷 / 02期
关键词：
CATALYZED ALPHA-ARYLATION; PHOTOREDOX CATALYSIS; KETONES; DIHYDROXYLATION; OXYALKYLATION; CONSTRUCTION; ALKYLATION; ALDEHYDES; CLEAVAGE; STYRENES;
D O I：
10.1039/c4cy01523a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A mild and efficient method for the photocatalytic oxidative arylation of vinylarenes to generate 1,2-diarylated ethanones has been developed. The reaction was catalyzed by Ru(bpy)(3)Cl-2 at room temperature under aerobic conditions. This protocol realizes a controllable, regioselective 1,2-difunctionalization of carbon-carbon double bonds.
引用
收藏
页码：830 / 834
页数：5
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