共 1 条
Sugar-derived building blocks, part 30.: A 2-C-fructosyl-propanone locked in a 2,7-dioxabicyclo[3.2.1]octane framework
被引:10
|作者:
Peters, S
[1
]
Lichtenthaler, FW
[1
]
Lindner, HJ
[1
]
机构:
[1] Tech Univ Darmstadt, Clemens Schopf Inst Organ Chem & Biochem, D-64287 Darmstadt, Germany
关键词:
D O I:
10.1016/S0957-4166(03)00501-9
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Condensation Of D-fructose with pentane-2,4-dione in mildly alkaline aqueous solution generates a novel sugar-based scaffold: a 2-C-fructosyl-propanone compressed by formation of a cycloacetal into a 2,7-dioxabicyclo[3.2.1]octane framework. (C) 2003 Elsevier Ltd. All rights reserved.
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页码:2475 / 2479
页数:5
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