Sugar-derived building blocks, part 30.: A 2-C-fructosyl-propanone locked in a 2,7-dioxabicyclo[3.2.1]octane framework

被引:10
|
作者
Peters, S [1 ]
Lichtenthaler, FW [1 ]
Lindner, HJ [1 ]
机构
[1] Tech Univ Darmstadt, Clemens Schopf Inst Organ Chem & Biochem, D-64287 Darmstadt, Germany
关键词
D O I
10.1016/S0957-4166(03)00501-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Condensation Of D-fructose with pentane-2,4-dione in mildly alkaline aqueous solution generates a novel sugar-based scaffold: a 2-C-fructosyl-propanone compressed by formation of a cycloacetal into a 2,7-dioxabicyclo[3.2.1]octane framework. (C) 2003 Elsevier Ltd. All rights reserved.
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页码:2475 / 2479
页数:5
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