Monodisperse and isolated microspheres of poly(N-methylaniline) prepared by dispersion polymerization

被引：7
|
作者：
Harima, Yutaka [1 ]
Sanada, Kei [1 ]
Patil, Rahul [1 ]
Ooyama, Yousuke [1 ]
Mizota, Haruo [2 ]
Yano, Jun [3 ]
机构：
[1] Hiroshima Univ, Grad Sch Engn, Hiroshima 7398527, Japan
[2] Hakodate Univ, Hakodate, Hokkaido 0420955, Japan
[3] Niihama Natl Coll Technol, Dept Engn Sci, Niihama, Ehime 7928580, Japan
来源：
EUROPEAN POLYMER JOURNAL | 2010年 / 46卷 / 07期
基金：
日本学术振兴会;
关键词：
Poly(N-methylaniline); Microspheres; Conducting polymer; Chemical polymerization; Morphology; ELECTROCHEMICAL PRODUCTION; CHEMICAL POLYMERIZATION; POLYANILINE; POLYPYRROLE; ANILINE; FABRICATION;
D O I：
10.1016/j.eurpolymj.2010.04.017
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Monodisperse and isolated microspheres of poly(N-methylaniline) were successfully prepared through chemical polymerization of N-methylaniline by S2O82- in adipic acid containing poly(vinylpyrrolidone) (PVP). Mean diameters of the microspheres with smooth surfaces changed from 320 to 100 nm by increasing the reaction temperature from 25 to 75 degrees C. The concentration of PVP did not affect much the size of microspheres, but the increased PVP concentration led to longer induction times for the onset of dispersion polymerization. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1480 / 1487
页数：8
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