Modeling of a bench-scale fixed-bed reactor for catalytic hydrotreating of vegetable oil

被引:9
|
作者
Tirado, Alexis [1 ]
Ancheyta, Jorge [2 ]
机构
[1] Inst Politecn Nacl, Ctr Invest Ciencia Aplicada & Tecnol Avanzada, Unidad Legaria, Legaria 694, Mexico City 11500, DF, Mexico
[2] Mexican Petr Inst, Lazar Cardenas Norte 152 Cent Axis, Mexico City 07730, DF, Mexico
关键词
Reactor modeling; Dynamic modeling; Vegetable oil hydrotreating; TRIGLYCERIDES; HYDROCRACKING; CONVERSION; KINETICS; DENSITY;
D O I
10.1016/j.renene.2019.10.164
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A dynamic trickle-bed reactor model was developed to predict the behavior of reactive species and products during the catalytic hydrotreating of vegetable oil. The prediction capability of the model was verified with experimental information obtained during the hydrotreating of a jatropha oil at temperature of 420 degrees C, hydrogen pressure of 80 bar, 1500 Nl/l of H-2/oil ratio and WHSV of 1-12 h(-1) using a NiW/SiO2-Al2O3 catalyst. The proposed model allows to predict the partial pressure and concentration profiles along the catalytic bed as a function of the time-on-stream. The dynamic simulation results agree with experimental data reported at steady-state conditions. A comparison of experimental data and calculated results provides a correlation coefficient of 0.988. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:790 / 797
页数:8
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