Dipraseodymium(III) pyroborate molybdate(VI), Pr2(B2O5)(MoO4)

被引：3
|
作者：
Held, Peter [1 ]
Becker, Petra [1 ]
机构：
[1] Univ Cologne, Inst Kristallog, D-50674 Cologne, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808010386
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of triclinic Pr-2(B2O5)(MoO4) were prepared from an incongruently melting flux in the system Pr2O3-MoO3-B2O3 in a platinum crucible in an atmosphere of air. In the crystal structure, distorted edge-sharing [PrO8] square antiprisms form a three-dimensional framework. These are further linked by isolated [MoO4] tetrahedra and isolated pyroborate groups [B2O5], the latter consisting of two independent trigonal [BO3] groups sharing one O atom. The [MoO4] tetrahedra and the [B2O5] groups are arranged in alternating layers parallel to the ab plane.
引用
收藏
页码：I28 / U10
页数：10
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