Heteroditopic Receptors for Ion-Pair Recognition

被引:213
|
作者
McConnell, Anna J. [1 ]
Beer, Paul D. [1 ]
机构
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
关键词
anions; cations; ion pairs; receptors; sensors; ALKALI-METAL CATIONS; DITOPIC RECEPTORS; ANION RECOGNITION; BINDING; SALTS; TRANSPORT; HALIDE; EXTRACTION; COMPLEXES; SOLVENT;
D O I
10.1002/anie.201107244
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ion-pair recognition is a new field of research emerging from cation and anion coordination chemistry. Specific types of heteroditopic receptor designs for ion pairs and the complexity of ion-pair binding are discussed to illustrate key concepts such as cooperativity. The importance of this area of research is reflected by the wide variety of potential applications of ion-pair receptors, including applications as membrane transport and salt solubilization agents and sensors.
引用
收藏
页码:5052 / 5061
页数:10
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