Copolymers derived from rapeseed derivatives via ADMET and thiol-ene addition

被引：55
|
作者：
Kreye, Oliver [1 ,2 ]
Toth, Tommy [2 ]
Meier, Michael A. R. [1 ,2 ]
机构：
[1] Karlsruhe Inst Technol, Inst Organ Chem, Lab Appl Chem, D-76131 Karlsruhe, Germany
[2] Univ Potsdam, Inst Chem, Lab Sustainable Organ Synth, D-14476 Golm, Germany
来源：
EUROPEAN POLYMER JOURNAL | 2011年 / 47卷 / 09期
关键词：
Rapeseed oil; Rapeseed cake; p-Hydroxycinnamic acids; alpha; omega-Dienes; ADMET polymerization; Thiol-ene addition; ACYCLIC DIENE METATHESIS; RENEWABLE RESOURCES; OLEFIN ISOMERIZATION; ACID-DERIVATIVES; POLYMER SCIENCE; BRASSICA-NAPUS; OIL; POLYMERIZATIONS; POLYESTERS; MONOMERS;
D O I：
10.1016/j.eurpolymj.2011.06.012
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Novel (co)polymers were synthesized from substances obtained from rapeseed via ADMET and thiol-ene additions. alpha,omega-Dienes derived from oleic and erucic acid were copolymerized with a ferulic acid derivative, a representative phenolic acid (p-hydroxycinnamic acid) present, for instance, in rapeseed cake. Copolymers with different ratios of these monomers were prepared via two different routes (ADMET and thiol-ene) and studied in detail. Both monomer and polymer synthesis were optimized in order to achieve high yielding synthetic procedures that meet the requirements of green chemistry. Some thermal properties of the resulting copolymer series were then studied and correlated to the co-monomer composition. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1804 / 1816
页数：13
相关论文
共 50 条
  • [1] Tuning the polarity of ADMET derived star-shaped polymers via thiol-ene chemistry
    Unverferth, Maike
    Meier, Michael A. R.
    [J]. POLYMER, 2014, 55 (22) : 5571 - 5575
  • [2] Highly Tunable Thiol-Ene Networks via Dual Thiol Addition
    McNair, Olivia. D.
    Sparks, Bradley J.
    Janisse, Andrew P.
    Brent, Davis P.
    Patton, Derek L.
    Savin, Daniel A.
    [J]. MACROMOLECULES, 2013, 46 (14) : 5614 - 5621
  • [3] Functional block copolymers via thiol-ene click chemistry
    Killops, Kato L.
    Gupta, Nalini
    Dimitriou, Michael D.
    Lynd, Nathaniel A.
    Jung, Hyunjung
    Bang, Joona
    Campos, Luis M.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [4] Synthesis of functional derivatives of stereoregular organocyclosilsesquioxanes by thiol-ene addition
    Vysochinskaya, Yulia
    Anisimov, Anton
    Krylov, Fedor
    Buzin, Mikhail
    Buzin, Alexander
    Peregudov, Alexander
    Shchegolikhina, Olga
    Muzafarov, Aziz
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2021, 954-955
  • [5] UNUSUAL ADDITION BY THE THIOL-ENE PHOTOPOLYMERIZATION
    KLEMM, E
    BEIL, U
    [J]. POLYMER BULLETIN, 1992, 28 (06) : 653 - 656
  • [6] Thiol-ene adhesives from clove oil derivatives
    Donovan, Brian R.
    Cobb, Jared S.
    Hoff, Ethan F. T.
    Patton, Derek L.
    [J]. RSC ADVANCES, 2014, 4 (106): : 61927 - 61935
  • [7] Thiol-ene films derived from phenolic acids
    Yang, Guozhen
    Tesefay, Hiruy
    Robertson, Megan
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [8] Functionalization of Polymer Nanoparticles by Thiol-Ene Addition
    Korthals, Brigitte
    Morant-Minana, Maria Carmen
    Schmid, Marius
    Mecking, Stefan
    [J]. MACROMOLECULES, 2010, 43 (19) : 8071 - 8078
  • [9] Cross-linking fluorene copolymers via thiol-ene click chemistry
    Chen, Xin-jie
    Li, Jian
    Wang, Chen-yi
    Ren, Qiang
    [J]. SYNTHETIC METALS, 2021, 282
  • [10] A versatile approach to the synthesis of polyphosphazene derivatives via the thiol-ene reaction
    Qian, Yue-Cheng
    Huang, Xiao-Jun
    Chen, Chen
    Ren, Ning
    Huang, Xu
    Xu, Zhi-Kang
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (24) : 5170 - 5176
12345