Determination of the enthalpy of fusion of K2NbF7 and K3NbF8

被引：0
|
作者：
Kosa, L [1 ]
Macková, I [1 ]
Chrenková, M [1 ]
机构：
[1] Slovak Acad Sci, Inst Inorgan Chem, SK-84536 Bratislava, Slovakia
来源：
CHEMICAL PAPERS | 2003年 / 57卷 / 05期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the basis of the areas of the fusion and crystallization peaks of K2NbF7 and K3NbF8 determined using the DSC mode of the high-temperature calorimeter (SETARAM 1800 K), and the temperature dependence of the calorimetric method sensitivity, the values of the enthalpy of fusion of K2NbF7 at equilibrium temperature of fusion 1008 K: Delta(fus)H(m)(K2NbF7) = (38 +/- 1) kJ mol(-1) and the enthalpy of fusion of K3NbF8 at equilibrium temperature of fusion 1043 K: Delta(fus)H(m)(K3NbF8) = (57 +/- 2) kJ mol(-1) have been determined.
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页码：301 / 303
页数：3
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