In the last few years, reactivity-controlled compression ignition (RCCI) mode combustion has gained researchers' attention due to its superior performance, combustion, and emission characteristics compared to other low-temperature combustion (LTC) strategies. In this study, RCCI mode combustion investigations were carried out to explore the effects of exhaust gas recirculation (EGR) and intake charge temperature (ICT) on combustion, performance, and emission characteristics of a mineral diesel/methanol-fueled engine. In this study, constant engine speed (1500 rpm) and load (3 bar brake mean effective pressure [BMEP]) were used to perform the engine experiments. The premixed ratio (r(p)) of methanol was varied from r(p) = 0 to r(p) = 0.75, where r(p) = 0 represents the baseline compression ignition (CI) mode combustion using diesel as fuel. At all r(p), EGR rate and ICT were varied from 0 to 30% and 40 degrees to 80 degrees C, respectively. Experimental results exhibited that increasing the EGR was useful in RCCI mode combustion up to medium r(p); however, at higher r(p), increasing the EGR resulted in incomplete combustion, leading to more hydrocarbon (HC) and carbon monoxide (CO) emissions. In contrast to EGR, increasing the ICT was more suitable at higher r(p), leading to a greater degree of combustion completion. Detailed particulate investigations were performed, which exhibited that increasing the r(p) resulted in relatively lesser particle emissions. At all r(p), increasing the EGR up to 15% led to relatively lower particle emissions; however, a higher EGR of 30% resulted in relatively higher particle emissions. Increasing the ICT resulted in higher particulate emissions; however, at higher r(p), EGR and ICT variations were less effective than lower r(p). Several qualitative correlations between different particulate characteristics revealed that intermediate EGR (15%) at intermediate ICT was the most suitable condition for optimized RCCI mode combustion.