Microporous mixed-metal mixed-ligand metal organic framework for selective CO2 capture

A microporous mixed-ligand-based metal-organic framework has been synthesized using two different dicarboxylic acid-based ligands (4,4-biphenyldicarboxylate (BPDC) and imino diacetate (IMDA)) and two different metal ions (Ce3+ and Na+), namely Ce3Na3(BPDC)(3)(IMDA)(3)(DMF)(2)(H2O)(9). The framework built from Ce-Na-carboxylate layers and BPDC pillars consists of 2D slit-shaped pores occupied by extra-framework Na+ ions. The desolvated framework is permanently porous with a BET surface area of approximate to 771 m(2) g(-1) and displays moderate CO2 uptake of 2.0 mmol g(-1) with a CO2/N-2 selectivity (S) of 68 at room temperature and 1 bar. A modest heat of adsorption (23 kJ mol(-1)) and smooth diffusion kinetics are observed, as reflected in the facile CO2 cycling. Using GCMC methods, the CO2 adsorption isotherm at 298 K was simulated, which matches the experimental isotherm well. The CO2 positions observed from the simulations showed that Na+ ions in the channels serve as favorable adsorption sites for the oxygen atoms in CO2 pointing toward the Na+ ions (O?C?ONa+ = 3.34-5.87 angstrom), while some CO2 molecules sit flat on the phenyl rings of the BPDC at a CO(2)centroid distance of 3.6-3.7 angstrom.