Poly[bis(N-methylformamide)tetra-μ-thiocyanato-manganese(II)-mercury(II)]

被引：5
|
作者：
Wang, XQ [1 ]
Yu, WT [1 ]
Xu, D [1 ]
Zhang, GH [1 ]
Geng, YL [1 ]
机构：
[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270105010814
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title complex, [MnHg(NCS)(4)(C2H5NO)(2)](n), consists of slightly distorted MnN4O2 octahedra and HgS4 tetrahedra. Each Mn-II cation is bound to four N atoms of the NCS groups and two O atoms of the N-methylformamide (NMF) ligands in a cis configuration. Each Hg-II cation is coordinated to four S atoms of NCS groups. Each pair of Mn-II and Hg-II cations is connected by an - NCS - bridge, forming an infinite three-dimensional - Mn - NCS - Hg - network.
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页码：M278 / M280
页数：3
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