Recent Progress in the Transition Metal Catalyzed Synthesis of Indoles

被引:54
|
作者
Mancuso, Raffaella [1 ]
Dalpozzo, Renato [1 ]
机构
[1] Univ Calabria, Dipartimento Chim & Tecnol Chim, I-87030 Arcavacata Di Rende, Cs, Italy
来源
CATALYSTS | 2018年 / 8卷 / 10期
关键词
metal catalysis; indoles; Diazo compounds; Alkynes; C-H activation; C-H ACTIVATION; N-N BOND; ONE-POT SYNTHESIS; 2,3-DISUBSTITUTED INDOLES; ALPHA-ARYLATION; 2-ALKYNYL ARYLAZIDES; TANDEM ADDITION/CYCLIZATION; RH(III)-CATALYZED SYNTHESIS; 1,2-DISUBSTITUTED INDOLES; REGIOSELECTIVE SYNTHESIS;
D O I
10.3390/catal8100458
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Indole is the most frequently found heterocyclic core structures in pharmaceuticals, natural products, agrochemicals, dyes and fragrances. For about 150 years, chemists were absorbed in finding new and easier synthetic strategies to build this nucleus. Many books and reviews have been written, but the number of new syntheses that appear in the literature, make necessary continuous updates. This reviews aims to give a comprehensive overview on indole synthesis catalyzed by transition metals appeared in the literature in the years 2016 and 2017.
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页数:64
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