Solution behavior and magnetic properties of a novel nonanuclear copper(II) cluster

被引：6

作者：

Ji, Bao-Qian ^{[1
]}

Jagodic, Marko ^{[6
]}

Ma, Hui-Yan ^{[2
,3
]}

Su, Hai-Feng ^{[4
,5
]}

Li, Yun-Wu ^{[2
,3
]}

Tung, Chen-Ho ^{[1
]}

Sun, Di ^{[1
,4
,5
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China

[2] Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252000, Peoples R China

[3] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Peoples R China

[4] Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

[5] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China

[6] Inst Math Phys & Mech, Jadranska 19, Ljubljana 1000, Slovenia

来源：

NEW JOURNAL OF CHEMISTRY | 2018年 / 42卷 / 22期

关键词：

OXYGEN-EVOLVING CENTER; MASS-SPECTROMETRY; COBALT-PIVALATE; CO-II; SYMMETRY; AGGREGATE; CHEMISTRY; COMPLEX;

D O I：

10.1039/c8nj04230f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel nonanuclear copper(II) nanocluster (Cu9) was constructed from a well-designed multidentate pyrazole-alcohol ligand and using various small anions. The Cu-9 skeleton was found to consist of two similar Cu-5 cluster units sharing one central Cu-II ion and to be protected by the outer organic ligand and auxiliary small anions. The solution behavior of Cu9 was studied in detail by applying the ESI-MS technique. Magnetism analysis implied the presence of antiferromagnetic interactions between the Cu-II ions.

引用

页码：17884 / 17888

页数：5

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