The bifurcation rearrangement in cyclic water clusters: Breaking and making hydrogen bonds

被引:51
|
作者
Brown, MG [1 ]
Keutsch, FN [1 ]
Saykally, RJ [1 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 22期
关键词
D O I
10.1063/1.477630
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Tunneling patterns observed in the vibration-rotation-tunnelling spectrum of (H2O)(5) measured near 2.7 THz established the time scale:For bifurcation rearrangements to be approximately 40 ns. This relatively local process is likely to be relevant in the dynamics of liquid water and ice. (C) 1998 American Institute of Physics. [S0021-9606(98)02146-1].
引用
收藏
页码:9645 / 9647
页数:3
相关论文
共 50 条
  • [1] Hydrogen delocalization in cyclic water clusters
    Mandziuk, M
    JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (01): : 121 - 126
  • [2] Hydrogen bonds in methane-water clusters
    Salazar-Cano, Juan-Ramon
    Guevara-Garcia, Alfredo
    Vargas, Rubicelia
    Restrepo, Albeiro
    Garza, Jorge
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (34) : 23508 - 23515
  • [3] The Subtleties of Dissolution and Regeneration of Cellulose: Breaking and Making Hydrogen Bonds
    Lindman, Bjoern
    Medronho, Bruno
    BIORESOURCES, 2015, 10 (03): : 3811 - 3814
  • [4] The making and breaking of bonds
    Antoine Browaeys
    Pierre Pillet
    Nature Physics, 2010, 6 : 941 - 942
  • [5] Cooperative organic hydrogen bonds: The librational modes of cyclic methanol clusters
    Larsen, R. Wugt
    Suhm, M. A.
    JOURNAL OF CHEMICAL PHYSICS, 2006, 125 (15):
  • [6] Making and breaking disulfide bonds
    Raina, S
    Missiakas, D
    ANNUAL REVIEW OF MICROBIOLOGY, 1997, 51 : 179 - 202
  • [7] MAKING AND BREAKING OF CHEMISORPTION BONDS
    LUNDQVIST, BI
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH, 1982, 198 (01): : 101 - 102
  • [8] Breaking rules–making bonds
    Samuelson A.G.
    Resonance, 2016, 21 (1) : 43 - 48
  • [9] TEMPERATURE BREAKING OF HYDROGEN-BONDS IN WATER BY NEGATIVE PION CAPTURE IN HYDROGEN
    KACHALKIN, AK
    KRUMSHTEIN, ZV
    MINKOVA, AP
    PETRUKHIN, VI
    SUVOROV, VM
    HORVAT, D
    YUTLANDOV, IA
    ZHURNAL EKSPERIMENTALNOI I TEORETICHESKOI FIZIKI, 1979, 77 (01): : 26 - 30
  • [10] Hydrogen delocalization in small cyclic water clusters.
    Mandziuk, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U339 - U339