Poly[disodium bis(μ-malonato)zincate(II)dihydrate]

被引：10
|
作者：
Lin, DD
Zhang, L
Xu, DJ [2 ]
机构：
[1] Hangzhou Inst Commerce, Dept Food Sci, Hangzhou, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803022153
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, {Na-2[Zn(C3H2O4)(2)].2H(2)O}(n), is a three-dimensional polymeric complex bridged by malonate dianions. The malonate ligand exhibits versatile coordination modes and links two Zn-II and four Na-I atoms. The Zn atom occupies a special position in an inversion centre and is chelated by two malonate ligands [Zn-O=2.0230 (10) and 2.0875 (11) Angstrom]; two other malonates are involved in monodentate coordination of the Zn atom [Zn-O=2.2789 (12) Angstrom], thus completing its octahedral coordination environment. The Na atom also has a distorted octahedral coordination, formed by four carboxylate O atoms of four malonate ligands [2.4328 (15)-2.5493 (13) Angstrom] and two water molecules [2.3749 (15) and 2.4144 (14) Angstrom].
引用
收藏
页码：M1010 / M1012
页数：3
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