Alloy design for lithium-ion battery anodes

被引：453
|
作者：
Obrovac, M. N. [1 ]
Christensen, Leif
Le, Dinh Ba
Dahnb, J. R.
机构：
[1] Elect Markets Mat Div, St Paul, MN 55105 USA
[2] Dalhousie Univ, Dept Phys, Halifax, NS B3H 3J5, Canada
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2007年 / 154卷 / 09期
关键词：
D O I：
10.1149/1.2752985
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A set of guidelines is proposed for designing high-energy-density alloy anode materials. It is first shown that the molar volume of lithium is about 9 mL/mol in a wide variety of lithium alloys and is independent of lithium content. Using this property of lithium alloys, simple relationships between the volumetric energy density and the volumetric expansion of an alloy are derived. These relationships are extremely powerful for designing alloys with the maximum possible energy density for a given electrode-coating performance. (C) 2007 The Electrochemical Society.
引用
收藏
页码：A849 / A855
页数：7
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